"Item of clothing patented by Mary Phelps Jacob in 1914" NYT crossword answer is:
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Mary Phelps Jacob patented the first modern brassiere in 1914. This revolutionary item of clothing was designed to replace the traditional corset and was made of two handkerchiefs and some ribbon. It was a revolutionary design that was quickly adopted by women all over the world and has since become an essential part of every woman's wardrobe.